| Group 4 | 01/03/1994 | Unión Española | - | Colo-Colo | 1:2 | ||||
| Group 4 | 22/03/1994 | Colo-Colo | - | Unión Española | 3:1 | ||||
| Group 4 | 11/04/1994 | Defensor Sporting | - | Unión Española | 1:1 | ||||
| Group 4 | 14/04/1994 | Nacional | - | Unión Española | 0:1 | ||||
| Quarter-finals | 28/07/1994 | Unión Española | - | São Paulo FC | 1:1 |  |
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| Quarter-finals | 02/08/1994 | São Paulo FC | - | Unión Española | 4:3 | |
Chile