| Group 4 | 01/03/1994 | Unión Española | - | Colo-Colo | 1:2 | ||||
| Group 4 | 07/03/1994 | Unión Española | - | Defensor Sporting | 1:0 | ||||
| Group 4 | 14/03/1994 | Unión Española | - | Nacional | 1:0 | ||||
| Group 4 | 22/03/1994 | Colo-Colo | - | Unión Española | 3:1 | ||||
| Group 4 | 11/04/1994 | Defensor Sporting | - | Unión Española | 1:1 | ||||
| Group 4 | 14/04/1994 | Nacional | - | Unión Española | 0:1 | ||||
| Round of 16 | 20/04/1994 | Unión Española | - | Cruzeiro | 1:0 | ||||
| Round of 16 | 27/04/1994 | Cruzeiro | - | Unión Española | 0:0 | ||||
| Quarter-finals | 28/07/1994 | Unión Española | - | São Paulo FC | 1:1 | ||||
| Quarter-finals | 02/08/1994 | São Paulo FC | - | Unión Española | 4:3 |  |
Chile