| 1. Round | 12/02/2020 | Deportivo Cali | - | River Plate | 2:1 |  |
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| 1. Round | 26/02/2020 | River Plate | - | Deportivo Cali | 1:3 | ||||
| 2. Round | 29/10/2020 | Millonarios | - | Deportivo Cali | 1:2 | ||||
| 2. Round | 05/11/2020 | Deportivo Cali | - | Millonarios | 5:4 pso | ||||
| Round of 16 | 25/11/2020 | Vélez Sarsfield | - | Deportivo Cali | 2:0 | ||||
| Round of 16 | 02/12/2020 | Deportivo Cali | - | Vélez Sarsfield | 1:5 | |
Colombia