| Group 1 | 14/02/2013 | Boca Juniors | - | Deportivo Toluca | 1:2 | ||||
| Group 1 | 27/02/2013 | Barcelona | - | Boca Juniors | 1:2 | ||||
| Group 1 | 14/03/2013 | Nacional | - | Boca Juniors | 0:1 | ||||
| Group 1 | 03/04/2013 | Boca Juniors | - | Barcelona | 1:0 |  |
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| Group 1 | 17/04/2013 | Deportivo Toluca | - | Boca Juniors | 3:2 |  |
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| Round of 16 | 02/05/2013 | Boca Juniors | - | Corinthians SP | 1:0 | |
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| Round of 16 | 16/05/2013 | Corinthians SP | - | Boca Juniors | 1:1 | ||||
| Quarter-finals | 24/05/2013 | Boca Juniors | - | Newell's Old Boys | 0:0 | ||||
| Quarter-finals | 29/05/2013 | Newell's Old Boys | - | Boca Juniors | 10:9 pso |
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