| 1. Round | 15/07/2007 | Arsenal Kiev | - | Metalurh Donetsk | 1:3 | ||||
| 3. Round | 29/07/2007 | Dnipro Dnipropetrovsk | - | Metalurh Donetsk | 4:1 |  |
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| 7. Round | 24/08/2007 | FK Kharkiv | - | Metalurh Donetsk | 1:1 | ||||
| 8. Round | 31/08/2007 | Tavriya Simferopol (1958-2014) | - | Metalurh Donetsk | 3:3 |  |
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| 10. Round | 21/09/2007 | Naftovik-Ukrnafta | - | Metalurh Donetsk | 2:2 |
Brazil