| 6. Round | 01/10/2005 | FC Barcelona | - | Real Zaragoza | 2:2 | ||||
| 8. Round | 22/10/2005 | FC Barcelona | - | CA Osasuna | 3:0 |  |
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| 11. Round | 26/10/2005 | FC Barcelona | - | Málaga CF | 2:0 | ||||
| 10. Round | 06/11/2005 | Getafe CF | - | FC Barcelona | 1:3 | ||||
| 12. Round | 19/11/2005 | Real Madrid | - | FC Barcelona | 0:3 | ||||
| 13. Round | 27/11/2005 | FC Barcelona | - | Racing Santander | 4:1 |  |
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| 14. Round | 04/12/2005 | Villarreal CF | - | FC Barcelona | 0:2 | ||||
| 15. Round | 11/12/2005 | FC Barcelona | - | Sevilla FC | 2:1 | |
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| 16. Round | 17/12/2005 | Cádiz CF | - | FC Barcelona | 1:3 | ||||
| 17. Round | 20/12/2005 | FC Barcelona | - | RC Celta | 2:0 | ||||
| 18. Round | 07/01/2006 | Espanyol Barcelona | - | FC Barcelona | 1:2 | ||||
| 19. Round | 15/01/2006 | FC Barcelona | - | Athletic Club | 2:1 | |
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| 20. Round | 22/01/2006 | FC Barcelona | - | CD Alavés | 2:0 | |
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| 21. Round | 29/01/2006 | RCD Mallorca | - | FC Barcelona | 0:3 | |
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| 22. Round | 05/02/2006 | FC Barcelona | - | Atlético Madrid | 1:3 | ||||
| 24. Round | 18/02/2006 | FC Barcelona | - | Real Betis | 5:1 | |
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| 25. Round | 25/02/2006 | Real Zaragoza | - | FC Barcelona | 0:2 |
Argentina
Spain 
