| 1. Round | 29/09/1940 | Hércules CF | - | Real Murcia | 4:0 |  |
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| 2. Round | 06/10/1940 | Real Madrid | - | Hércules CF | 5:3 | ||||
| 3. Round | 13/10/1940 | Hércules CF | - | Athletic Club | 1:0 | ||||
| 4. Round | 20/10/1940 | FC Barcelona | - | Hércules CF | 3:2 | |
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| 6. Round | 03/11/1940 | Real Zaragoza | - | Hércules CF | 7:0 | ||||
| 7. Round | 10/11/1940 | Sevilla FC | - | Hércules CF | 8:3 | |
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| 8. Round | 17/11/1940 | Hércules CF | - | Atlético Aviación | 3:3 | |
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| 9. Round | 24/11/1940 | Espanyol Barcelona | - | Hércules CF | 1:2 | ||||
| 10. Round | 01/12/1940 | Hércules CF | - | Real Oviedo | 3:0 | ||||
| 13. Round | 22/12/1940 | Hércules CF | - | Real Madrid | 0:3 | ||||
| 15. Round | 05/01/1941 | Hércules CF | - | FC Barcelona | 1:3 | ||||
| 16. Round | 19/01/1941 | Valencia CF | - | Hércules CF | 6:0 | ||||
| 19. Round | 09/02/1941 | Atlético Aviación | - | Hércules CF | 7:1 | ||||
| 21. Round | 23/02/1941 | Real Oviedo | - | Hércules CF | 6:0 | ||||
| 22. Round | 02/03/1941 | Hércules CF | - | RC Celta | 0:5 |
Spain