| 1. Round | 08/08/2009 | Valenciennes FC | - | AS Nancy Lorraine | 1:3 |  |
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| 2. Round | 15/08/2009 | Olympique Lyonnais | - | Valenciennes FC | 1:0 | ||||
| 3. Round | 22/08/2009 | Valenciennes FC | - | Paris Saint-Germain | 2:3 | ||||
| 4. Round | 30/08/2009 | Toulouse FC | - | Valenciennes FC | 0:1 | |
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| 5. Round | 12/09/2009 | Valenciennes FC | - | US Boulogne | 1:1 | ||||
| 7. Round | 26/09/2009 | Valenciennes FC | - | Olympique Marseille | 3:2 | ||||
| 8. Round | 03/10/2009 | OGC Nice | - | Valenciennes FC | 3:2 | |
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| 9. Round | 17/10/2009 | Valenciennes FC | - | Grenoble Foot 38 | 2:0 | |
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| 14. Round | 21/11/2009 | Girondins Bordeaux | - | Valenciennes FC | 0:1 | |
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| 15. Round | 28/11/2009 | Lille OSC | - | Valenciennes FC | 4:0 | ||||
| 16. Round | 05/12/2009 | Valenciennes FC | - | AS Monaco | 3:1 | |
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| 17. Round | 12/12/2009 | Le Mans UC 72 | - | Valenciennes FC | 2:1 |  |
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| 11. Round | 15/12/2009 | Valenciennes FC | - | AJ Auxerre | 0:0 | ||||
| 31. Round | 03/04/2010 | Valenciennes FC | - | Lille OSC | 1:0 | |
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| 32. Round | 10/04/2010 | AS Monaco | - | Valenciennes FC | 2:1 | ||||
| 30. Round | 28/04/2010 | Valenciennes FC | - | Girondins Bordeaux | 2:0 | ||||
| 35. Round | 02/05/2010 | Valenciennes FC | - | FC Lorient | 0:0 |
France