| 2. Round | 11/09/2005 | Real Zaragoza | - | Valencia CF | 2:2 | ||||
| 4. Round | 21/09/2005 | FC Barcelona | - | Valencia CF | 2:2 | ||||
| 5. Round | 24/09/2005 | Valencia CF | - | Real Sociedad | 2:1 | ||||
| 7. Round | 16/10/2005 | Valencia CF | - | Málaga CF | 2:1 | ||||
| 9. Round | 30/10/2005 | Valencia CF | - | Racing Santander | 1:1 |
Italy