| 1. Round | 24/08/1990 | MVV | - | NEC Nijmegen | 1:2 | ||||
| 2. Round | 01/09/1990 | Feyenoord | - | MVV | 6:0 | ||||
| 3. Round | 07/09/1990 | PSV Eindhoven | - | MVV | 3:0 | ||||
| 4. Round | 14/09/1990 | MVV | - | sc Heerenveen | 2:0 | ||||
| 5. Round | 22/09/1990 | RKC Waalwijk | - | MVV | 3:2 | ||||
| 6. Round | 29/09/1990 | MVV | - | AFC Ajax | 1:4 | ||||
| 7. Round | 07/10/1990 | FC Den Haag | - | MVV | 5:1 | ||||
| 10. Round | 02/11/1990 | MVV | - | SVV Schiedam | 2:0 | ||||
| 21. Round | 01/03/1991 | sc Heerenveen | - | MVV | 1:0 | ||||
| 22. Round | 08/03/1991 | MVV | - | RKC Waalwijk | 0:1 | ||||
| 25. Round | 14/03/1991 | Roda JC Kerkrade | - | MVV | 1:0 | ||||
| 23. Round | 31/03/1991 | AFC Ajax | - | MVV | 1:0 |  |
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| 26. Round | 05/04/1991 | MVV | - | Sparta Rotterdam | 0:0 | |
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| 18. Round | 08/04/1991 | NEC Nijmegen | - | MVV | 2:1 | ||||
| 27. Round | 18/04/1991 | SVV Schiedam | - | MVV | 1:4 | ||||
| 28. Round | 25/04/1991 | MVV | - | Vitesse | 2:0 | ||||
| 19. Round | 30/04/1991 | MVV | - | Feyenoord | 0:2 | ||||
| 29. Round | 04/05/1991 | Willem II | - | MVV | 0:1 | ||||
| 20. Round | 08/05/1991 | MVV | - | PSV Eindhoven | 3:3 | ||||
| 30. Round | 11/05/1991 | MVV | - | Fortuna Sittard | 1:1 | ||||
| 31. Round | 17/05/1991 | FC Twente | - | MVV | 4:1 | ||||
| 33. Round | 08/06/1991 | FC Volendam | - | MVV | 2:2 | ||||
| 34. Round | 15/06/1991 | MVV | - | FC Utrecht | 1:1 |
Netherlands