| 1. Round | 18/10/2020 | Peña Deportiva | - | Villarreal CF B | 1:0 |  |
|||
| 2. Round | 24/10/2020 | Villarreal CF B | - | Levante UD B | 1:1 | ||||
| 3. Round | 01/11/2020 | CF La Nucía | - | Villarreal CF B | 1:2 | ||||
| 5. Round | 21/11/2020 | Atzeneta UE | - | Villarreal CF B | 1:1 | ||||
| 4. Round | 25/11/2020 | Villarreal CF B | - | CD Alcoyano | 3:0 | ||||
| 6. Round | 29/11/2020 | Villarreal CF B | - | Valencia CF B | 1:1 | ||||
| 7. Round | 06/12/2020 | Hércules CF | - | Villarreal CF B | 0:0 | ||||
| 8. Round | 13/12/2020 | Villarreal CF B | - | Orihuela CF | 2:0 | |
|||
| 9. Round | 10/01/2021 | UD Ibiza | - | Villarreal CF B | 2:0 | ||||
| 10. Round | 20/01/2021 | Villarreal CF B | - | Peña Deportiva | 2:0 | ||||
| 11. Round | 24/01/2021 | Levante UD B | - | Villarreal CF B | 0:0 | |
|||
| 12. Round | 30/01/2021 | Villarreal CF B | - | CF La Nucía | 0:1 | |
Uruguay
Italy