| 1. Round | 20/08/2006 | PSV Eindhoven | - | NEC Nijmegen | 3:1 | ||||
| 2. Round | 27/08/2006 | FC Twente | - | PSV Eindhoven | 1:0 |  |
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| 4. Round | 17/09/2006 | PSV Eindhoven | - | Feyenoord | 2:1 | ||||
| 5. Round | 23/09/2006 | ADO Den Haag | - | PSV Eindhoven | 0:2 | ||||
| 7. Round | 15/10/2006 | PSV Eindhoven | - | Roda JC Kerkrade | 4:1 | |
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| 9. Round | 25/10/2006 | PSV Eindhoven | - | Sparta Rotterdam | 7:0 | ||||
| 10. Round | 28/10/2006 | RKC Waalwijk | - | PSV Eindhoven | 0:3 |
Netherlands
Nigeria