1. Round 21/08/1999 FC Barcelona - Real Zaragoza 2:0
2. Round 28/08/1999 Racing Santander - FC Barcelona 1:2
3. Round 10/09/1999 FC Barcelona - Espanyol Barcelona 3:0
5. Round 24/09/1999 FC Barcelona - Real Betis 4:1
7. Round 12/10/1999 FC Barcelona - Real Madrid 2:2 yellow card
9. Round 22/10/1999 FC Barcelona - Athletic Club 4:0
10. Round 29/10/1999 Deportivo La Coruña - FC Barcelona 2:1
11. Round 06/11/1999 FC Barcelona - Málaga CF 1:2
12. Round 19/11/1999 Valencia CF - FC Barcelona 3:1
13. Round 27/11/1999 RCD Mallorca - FC Barcelona 3:2
14. Round 03/12/1999 FC Barcelona - Real Oviedo 3:2
15. Round 10/12/1999 Sevilla FC - FC Barcelona 3:2
16. Round 18/12/1999 FC Barcelona - Atlético Madrid 2:1
17. Round 21/12/1999 Rayo Vallecano - FC Barcelona 1:1
18. Round 04/01/2000 FC Barcelona - Real Sociedad 3:1
19. Round 08/01/2000 RC Celta - FC Barcelona 0:2
20. Round 15/01/2000 Real Zaragoza - FC Barcelona 0:0
21. Round 22/01/2000 FC Barcelona - Racing Santander 1:0
23. Round 05/02/2000 FC Barcelona - CD Alavés 0:1
24. Round 12/02/2000 Real Betis - FC Barcelona 2:1
25. Round 19/02/2000 FC Barcelona - Real Valladolid 4:0
26. Round 25/02/2000 Real Madrid - FC Barcelona 3:0 yellow card
27. Round 03/03/2000 FC Barcelona - CD Numancia 4:0
31. Round 01/04/2000 FC Barcelona - Valencia CF 3:0 yellow card
33. Round 14/04/2000 Real Oviedo - FC Barcelona 3:0
34. Round 21/04/2000 FC Barcelona - Sevilla FC 2:0
35. Round 28/04/2000 Atlético Madrid - FC Barcelona 0:3
37. Round 13/05/2000 Real Sociedad - FC Barcelona 0:0 yellow card
38. Round 18/05/2000 FC Barcelona - RC Celta 2:2 yellow card