| Group C | 12/09/2006 | PSV Eindhoven | - | Liverpool FC | 0:0 | ||||
| Group C | 27/09/2006 | Girondins Bordeaux | - | PSV Eindhoven | 0:1 |  |
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| Group C | 18/10/2006 | Galatasaray | - | PSV Eindhoven | 1:2 | ||||
| Group C | 31/10/2006 | PSV Eindhoven | - | Galatasaray | 2:0 | ||||
| Round of 16 | 20/02/2007 | PSV Eindhoven | - | Arsenal FC | 1:0 | ||||
| Round of 16 | 07/03/2007 | Arsenal FC | - | PSV Eindhoven | 1:1 | ||||
| Quarter-finals | 03/04/2007 | PSV Eindhoven | - | Liverpool FC | 0:3 | ||||
| Quarter-finals | 11/04/2007 | Liverpool FC | - | PSV Eindhoven | 1:0 |
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