| 3. Round | 27/09/2020 | FC Barcelona | - | Villarreal CF | 4:0 | ||||
| 5. Round | 04/10/2020 | FC Barcelona | - | Sevilla FC | 1:1 |  |
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| 8. Round | 31/10/2020 | CD Alavés | - | FC Barcelona | 1:1 | ||||
| 9. Round | 07/11/2020 | FC Barcelona | - | Real Betis | 5:2 | ||||
| 10. Round | 21/11/2020 | Atlético Madrid | - | FC Barcelona | 1:0 | ||||
| 12. Round | 05/12/2020 | Cádiz CF | - | FC Barcelona | 2:1 | ||||
| 19. Round | 16/12/2020 | FC Barcelona | - | Real Sociedad | 2:1 | ||||
| 14. Round | 19/12/2020 | FC Barcelona | - | Valencia CF | 2:2 | ||||
| 15. Round | 22/12/2020 | Real Valladolid | - | FC Barcelona | 0:3 | ||||
| 16. Round | 29/12/2020 | FC Barcelona | - | SD Eibar | 1:1 | ||||
| 17. Round | 03/01/2021 | SD Huesca | - | FC Barcelona | 0:1 | ||||
| 18. Round | 09/01/2021 | Granada CF | - | FC Barcelona | 0:4 | ||||
| 21. Round | 31/01/2021 | FC Barcelona | - | Athletic Club | 2:1 | ||||
| 22. Round | 07/02/2021 | Real Betis | - | FC Barcelona | 2:3 | ||||
| 23. Round | 13/02/2021 | FC Barcelona | - | CD Alavés | 5:1 | ||||
| 24. Round | 21/02/2021 | FC Barcelona | - | Cádiz CF | 1:1 | ||||
| 1. Round | 24/02/2021 | FC Barcelona | - | Elche CF | 3:0 | ||||
| 37. Round | 16/05/2021 | FC Barcelona | - | RC Celta | 1:2 | ||||
| 38. Round | 22/05/2021 | SD Eibar | - | FC Barcelona | 0:1 |
Bosnia-Herzegovina
Luxembourg 
