| 16. Round | 14/02/2021 | Rayo Vallecano [Women] | - | Espanyol Barcelona [Women] | 2:0 | ||||
| 21. Round | 07/03/2021 | Real Madrid [Women] | - | Espanyol Barcelona [Women] | 4:1 | ||||
| 22. Round | 13/03/2021 | Espanyol Barcelona [Women] | - | Santa Teresa CD [Women] | 1:2 | ||||
| 20. Round | 17/03/2021 | Espanyol Barcelona [Women] | - | UDG Tenerife Sur [Women] | 2:3 | ||||
| 23. Round | 20/03/2021 | SD Eibar [Women] | - | Espanyol Barcelona [Women] | 0:1 | ||||
| 24. Round | 28/03/2021 | Espanyol Barcelona [Women] | - | Real Sociedad [Women] | 0:4 | ||||
| 25. Round | 04/04/2021 | Real Betis [Women] | - | Espanyol Barcelona [Women] | 0:0 | ||||
| 26. Round | 17/04/2021 | Espanyol Barcelona [Women] | - | Rayo Vallecano [Women] | 2:2 |  |
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| 30. Round | 15/05/2021 | Deportivo La Coruña [Women] | - | Espanyol Barcelona [Women] | 2:1 | |
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