| 3. Round | 25/07/2004 | Vorskla-Naftohaz | - | Metalist Kharkiv | 0:1 | ||||
| 4. Round | 01/08/2004 | Metalist Kharkiv | - | Borysfen Boryspil | 3:1 | ||||
| 5. Round | 14/08/2004 | Metalurg Zaporizhya | - | Metalist Kharkiv | 1:4 | ||||
| 6. Round | 29/08/2004 | Metalist Kharkiv | - | Arsenal Kiev | 1:1 | ||||
| 10. Round | 24/10/2004 | Shakhtar Donetsk | - | Metalist Kharkiv | 0:1 | ||||
| 11. Round | 30/10/2004 | Metalist Kharkiv | - | Zakarpattya Uzhgorod | 1:0 | ||||
| 12. Round | 07/11/2004 | Volyn Lutsk | - | Metalist Kharkiv | 4:2 | ||||
| 13. Round | 11/11/2004 | Metalist Kharkiv | - | FK Illichivets | 1:0 | ||||
| 14. Round | 28/11/2004 | Dinamo Kiev | - | Metalist Kharkiv | 3:0 |
Ukraine