| 1. Round | 27/08/2006 | Athletic Club | - | Real Sociedad | 1:1 | ||||
| 4. Round | 24/09/2006 | Getafe CF | - | Athletic Club | 0:0 |  |
|||
| 5. Round | 30/09/2006 | Athletic Club | - | FC Barcelona | 1:3 | ||||
| 6. Round | 15/10/2006 | Gimnàstic de Tarragona | - | Athletic Club | 2:3 | ||||
| 9. Round | 05/11/2006 | Athletic Club | - | Racing Santander | 0:0 | ||||
| 10. Round | 11/11/2006 | Valencia CF | - | Athletic Club | 1:1 | |
|||
| 11. Round | 19/11/2006 | Espanyol Barcelona | - | Athletic Club | 3:2 | |
|||
| 12. Round | 26/11/2006 | Athletic Club | - | Sevilla FC | 1:3 | ||||
| 13. Round | 03/12/2006 | Real Madrid | - | Athletic Club | 2:1 | ||||
| 20. Round | 28/01/2007 | Real Sociedad | - | Athletic Club | 0:2 |
Spain