| Copa Lib. | 07/04/63 | Club Olimpia | - | Boca Juniors | 1:0 | ||||
| Copa Lib. | 14/04/63 | Boca Juniors | - | Club Olimpia | 5:3 |  |
|||
| Copa Lib. | 14/02/65 | The Strongest | - | Boca Juniors | 2:3 |
| Copa Lib. | 07/04/63 | Club Olimpia | - | Boca Juniors | 1:0 | ||||
| Copa Lib. | 14/04/63 | Boca Juniors | - | Club Olimpia | 5:3 | |
|||
| Copa Lib. | 14/02/65 | The Strongest | - | Boca Juniors | 2:3 |
| Paulo Valentim | |
| Born: | 20.11.1932 † 09.07.1984 |
| Place of birth: |
Barra do Piraí, 
Brazil |
| Nationality: |
Brazil
|
| Height: | 181 cm |
| Weight: | 76 kg |