| 2. Round | 07/09/1996 | Real Madrid | - | Hércules CF | 3:0 | ||||
| 3. Round | 14/09/1996 | Hércules CF | - | RC Celta | 0:2 |  |
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| 4. Round | 21/09/1996 | Deportivo La Coruña | - | Hércules CF | 4:0 | ||||
| 5. Round | 29/09/1996 | Atlético Madrid | - | Hércules CF | 3:0 | ||||
| 6. Round | 01/10/1996 | Hércules CF | - | Real Betis | 0:1 | ||||
| 7. Round | 12/10/1996 | Rayo Vallecano | - | Hércules CF | 2:1 | ||||
| 8. Round | 18/10/1996 | Hércules CF | - | Real Oviedo | 1:1 | ||||
| 9. Round | 22/10/1996 | Espanyol Barcelona | - | Hércules CF | 2:1 | ||||
| 10. Round | 26/10/1996 | Hércules CF | - | Racing Santander | 0:1 | ||||
| 11. Round | 02/11/1996 | Real Sociedad | - | Hércules CF | 2:1 | ||||
| 13. Round | 15/11/1996 | CD Tenerife | - | Hércules CF | 3:1 | |
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| 19. Round | 12/01/1997 | FC Barcelona | - | Hércules CF | 2:3 | ||||
| 21. Round | 25/01/1997 | Athletic Club | - | Hércules CF | 5:0 |
Austria