| 1. Round | 30/07/2022 | Heart of Midlothian | - | Ross County FC | 2:1 | ||||
| 2. Round | 07/08/2022 | Hibernian FC | - | Heart of Midlothian | 1:1 |  |
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| 3. Round | 14/08/2022 | Heart of Midlothian | - | Dundee United | 4:1 | ||||
| 4. Round | 21/08/2022 | Celtic FC | - | Heart of Midlothian | 2:0 | ||||
| 5. Round | 28/08/2022 | Heart of Midlothian | - | St. Johnstone FC | 3:2 | ||||
| 6. Round | 03/09/2022 | Livingston FC | - | Heart of Midlothian | 1:0 | ||||
| 8. Round | 18/09/2022 | Motherwell FC | - | Heart of Midlothian | 0:3 | ||||
| 9. Round | 01/10/2022 | Heart of Midlothian | - | Rangers FC | 0:4 | ||||
| 11. Round | 16/10/2022 | Aberdeen FC | - | Heart of Midlothian | 2:0 | ||||
| 31. Round | 08/04/2023 | Heart of Midlothian | - | St. Mirren FC | 0:2 | ||||
| 33. Round | 22/04/2023 | Heart of Midlothian | - | Ross County FC | 6:1 |
Austria