| 1. Round | 29/07/2006 | Dunfermline Athletic | - | Heart of Midlothian | 1:2 | ||||
| 2. Round | 06/08/2006 | Heart of Midlothian | - | Celtic FC | 2:1 | ||||
| 3. Round | 12/08/2006 | Heart of Midlothian | - | Falkirk FC | 0:0 | ||||
| 4. Round | 19/08/2006 | Rangers FC | - | Heart of Midlothian | 2:0 |  |
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| 6. Round | 09/09/2006 | Heart of Midlothian | - | St. Mirren FC | 0:1 | ||||
| 7. Round | 17/09/2006 | Motherwell FC | - | Heart of Midlothian | 0:1 | ||||
| 11. Round | 21/10/2006 | Heart of Midlothian | - | Kilmarnock FC | 0:2 |  |
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| 12. Round | 28/10/2006 | Heart of Midlothian | - | Dunfermline Athletic | 1:1 | |
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| 13. Round | 04/11/2006 | Celtic FC | - | Heart of Midlothian | 2:1 | |
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| 16. Round | 25/11/2006 | Inverness CT | - | Heart of Midlothian | 0:0 | ||||
| 17. Round | 02/12/2006 | St. Mirren FC | - | Heart of Midlothian | 2:2 | ||||
| 20. Round | 23/12/2006 | Dundee United | - | Heart of Midlothian | 0:1 | ||||
| 22. Round | 30/12/2006 | Kilmarnock FC | - | Heart of Midlothian | 0:0 | |
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| 23. Round | 02/01/2007 | Dunfermline Athletic | - | Heart of Midlothian | 0:1 |
Scotland
