| 1. Round | 25/08/1990 | AFC Ajax | - | Willem II | 3:1 | ||||
| 3. Round | 08/09/1990 | AFC Ajax | - | FC Twente | 1:1 | ||||
| 6. Round | 29/09/1990 | MVV | - | AFC Ajax | 1:4 |  |
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| 7. Round | 07/10/1990 | AFC Ajax | - | NEC Nijmegen | 7:0 | ||||
| 15. Round | 12/01/1991 | Sparta Rotterdam | - | AFC Ajax | 0:0 | ||||
| 18. Round | 02/02/1991 | Willem II | - | AFC Ajax | 3:2 | ||||
| 25. Round | 16/03/1991 | AFC Ajax | - | FC Utrecht | 1:1 | ||||
| 12. Round | 18/03/1991 | Roda JC Kerkrade | - | AFC Ajax | 0:0 | ||||
| 24. Round | 23/03/1991 | NEC Nijmegen | - | AFC Ajax | 0:5 | ||||
| 26. Round | 06/04/1991 | PSV Eindhoven | - | AFC Ajax | 4:1 | ||||
| 20. Round | 14/05/1991 | FC Twente | - | AFC Ajax | 0:1 | ||||
| 22. Round | 25/05/1991 | FC Volendam | - | AFC Ajax | 0:3 | ||||
| 33. Round | 08/06/1991 | SVV Schiedam | - | AFC Ajax | 1:0 | ||||
| 34. Round | 15/06/1991 | AFC Ajax | - | Vitesse | 3:0 |
Netherlands