| Group 7 | 27/03/2014 | Club León | - | Bolívar | 0:1 | ||||
| Group 7 | 09/04/2014 | Bolívar | - | Emelec | 2:1 | ||||
| Round of 16 | 17/04/2014 | Club León | - | Bolívar | 2:2 | ||||
| Round of 16 | 23/04/2014 | Bolívar | - | Club León | 1:1 |  |
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| Quarter-finals | 08/05/2014 | Lanús | - | Bolívar | 1:1 |  |
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| Quarter-finals | 15/05/2014 | Bolívar | - | Lanús | 1:0 | ||||
| Semi-finals | 23/07/2014 | San Lorenzo | - | Bolívar | 5:0 | ||||
| Semi-finals | 31/07/2014 | Bolívar | - | San Lorenzo | 1:0 |
Bolivia