| 1. Round | 20/08/2006 | PSV Eindhoven | - | NEC Nijmegen | 3:1 | ||||
| 2. Round | 27/08/2006 | FC Twente | - | PSV Eindhoven | 1:0 | ||||
| 5. Round | 23/09/2006 | ADO Den Haag | - | PSV Eindhoven | 0:2 | ||||
| 6. Round | 01/10/2006 | sc Heerenveen | - | PSV Eindhoven | 0:0 | ||||
| 7. Round | 15/10/2006 | PSV Eindhoven | - | Roda JC Kerkrade | 4:1 |  |
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| 8. Round | 22/10/2006 | AZ Alkmaar | - | PSV Eindhoven | 1:3 | ||||
| 13. Round | 18/11/2006 | PSV Eindhoven | - | SBV Excelsior | 4:0 |
Netherlands