| 1. Round | 13/07/2013 | Metalurg Zaporizhya | - | FK Illichivets | 0:1 |  |
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| 2. Round | 19/07/2013 | FK Illichivets | - | Dnipro Dnipropetrovsk | 0:2 |  |
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| 3. Round | 26/07/2013 | Metalist Kharkiv | - | FK Illichivets | 2:0 | ||||
| 4. Round | 02/08/2013 | FK Illichivets | - | Karpaty Lviv | 1:1 | ||||
| 5. Round | 10/08/2013 | Vorskla Poltava | - | FK Illichivets | 1:0 | ||||
| 6. Round | 17/08/2013 | FK Illichivets | - | Metalurh Donetsk | 3:0 | ||||
| 11. Round | 29/09/2013 | FK Illichivets | - | Hoverla Uzhgorod | 0:1 | ||||
| 12. Round | 06/10/2013 | PFK Sevastopol | - | FK Illichivets | 0:1 | ||||
| 13. Round | 19/10/2013 | FK Illichivets | - | Shakhtar Donetsk | 1:3 | ||||
| 14. Round | 27/10/2013 | Dinamo Kiev | - | FK Illichivets | 1:0 | ||||
| 15. Round | 02/11/2013 | FK Illichivets | - | Tavriya Simferopol (1958-2014) | 1:2 | |
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| 16. Round | 08/11/2013 | FK Illichivets | - | Metalurg Zaporizhya | 3:1 | ||||
| 17. Round | 23/11/2013 | Dnipro Dnipropetrovsk | - | FK Illichivets | 3:1 | ||||
| 21. Round | 15/03/2014 | Metalurh Donetsk | - | FK Illichivets | 1:1 | ||||
| 23. Round | 30/03/2014 | FK Illichivets | - | Chernomorets Odessa | 3:1 | ||||
| 24. Round | 06/04/2014 | Zorya Lugansk | - | FK Illichivets | 3:0 |
Ukraine