| 6. Round | 20/08/2005 | Metalist Kharkiv | - | Shakhtar Donetsk | 1:5 |  |
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| 8. Round | 11/09/2005 | Arsenal Kiev | - | Shakhtar Donetsk | 0:0 |  |
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| 9. Round | 18/09/2005 | Shakhtar Donetsk | - | Stal Alchevsk | 1:1 | ||||
| 17. Round | 27/11/2005 | Dnipro Dnipropetrovsk | - | Shakhtar Donetsk | 2:2 | ||||
| 18. Round | 05/12/2005 | Shakhtar Donetsk | - | FK Kharkiv | 3:0 | ||||
| 19. Round | 10/12/2005 | FK Krivbas (old) | - | Shakhtar Donetsk | 0:2 |
Ukraine