| Group 3 | 14/02/2006 | Unión Española | - | Goiás - GO | 0:2 | ||||
| Group 3 | 21/02/2006 | Newell's Old Boys | - | Unión Española | 2:0 | ||||
| Group 3 | 01/03/2006 | Unión Española | - | The Strongest | 1:0 | ||||
| Group 3 | 12/04/2006 | Unión Española | - | Newell's Old Boys | 1:1 |  |
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| Group 3 | 19/04/2006 | Goiás - GO | - | Unión Española | 0:0 |
Chile