| 1. Round | 20/08/1994 | 1. FSV Mainz 05 | - | FC 08 Homburg | 4:1 | ||||
| 3. Round | 26/08/1994 | 1. FSV Mainz 05 | - | Hansa Rostock | 2:2 |  |
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| 4. Round | 03/09/1994 | Waldhof Mannheim | - | 1. FSV Mainz 05 | 4:0 | |
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| 7. Round | 01/10/1994 | 1. FSV Mainz 05 | - | Fortuna Düsseldorf | 0:2 | ||||
| 9. Round | 15/10/1994 | 1. FSV Mainz 05 | - | 1. FC Saarbrücken | 1:1 | ||||
| 10. Round | 21/10/1994 | SG Wattenscheid 09 | - | 1. FSV Mainz 05 | 3:2 | ||||
| 13. Round | 12/11/1994 | 1. FSV Mainz 05 | - | Hertha BSC | 1:1 | |
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| 14. Round | 20/11/1994 | FC St. Pauli | - | 1. FSV Mainz 05 | 3:1 | ||||
| 27. Round | 23/04/1995 | 1. FSV Mainz 05 | - | SG Wattenscheid 09 | 2:0 | ||||
| 28. Round | 29/04/1995 | Hannover 96 | - | 1. FSV Mainz 05 | 2:0 | |
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| 19. Round | 02/05/1995 | 1. FSV Mainz 05 | - | VfL Wolfsburg | 2:0 | ||||
| 29. Round | 06/05/1995 | 1. FSV Mainz 05 | - | 1. FC Nürnberg | 1:0 | |
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| 31. Round | 20/05/1995 | 1. FSV Mainz 05 | - | FC St. Pauli | 1:1 |  |
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| 32. Round | 27/05/1995 | Fortuna Köln | - | 1. FSV Mainz 05 | 3:1 | |
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| 33. Round | 11/06/1995 | FSV Zwickau | - | 1. FSV Mainz 05 | 2:1 | |
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| 34. Round | 18/06/1995 | 1. FSV Mainz 05 | - | FSV Frankfurt | 7:1 | |
Russia