| 1. Round | 12/07/2005 | FK Illichivets | - | Metalist Kharkiv | 0:2 | ||||
| 2. Round | 17/07/2005 | FK Illichivets | - | Vorskla Poltava | 3:2 |  |
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| 3. Round | 23/07/2005 | Metalurh Donetsk | - | FK Illichivets | 0:0 | ||||
| 4. Round | 31/07/2005 | FK Illichivets | - | Chernomorets Odessa | 0:1 | ||||
| 5. Round | 08/08/2005 | Dinamo Kiev | - | FK Illichivets | 1:1 | |
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| 6. Round | 21/08/2005 | FK Illichivets | - | Volyn Lutsk | 1:1 | ||||
| 7. Round | 29/08/2005 | Dnipro Dnipropetrovsk | - | FK Illichivets | 0:1 | ||||
| 8. Round | 11/09/2005 | FK Illichivets | - | FK Kharkiv | 2:1 | ||||
| 9. Round | 18/09/2005 | FK Krivbas (old) | - | FK Illichivets | 0:1 |  |
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| 10. Round | 25/09/2005 | FK Illichivets | - | Tavriya Simferopol (1958-2014) | 0:1 | ||||
| 11. Round | 03/10/2005 | Shakhtar Donetsk | - | FK Illichivets | 6:0 | ||||
| 12. Round | 16/10/2005 | FK Illichivets | - | Metalurg Zaporizhya | 1:0 | ||||
| 16. Round | 20/11/2005 | Metalist Kharkiv | - | FK Illichivets | 1:1 |
Ukraine