| 1. Round | 25/08/1990 | AFC Ajax | - | Willem II | 3:1 |  |
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| 2. Round | 30/08/1990 | Fortuna Sittard | - | AFC Ajax | 1:1 | ||||
| 3. Round | 08/09/1990 | AFC Ajax | - | FC Twente | 1:1 | ||||
| 4. Round | 15/09/1990 | FC Groningen | - | AFC Ajax | 1:2 | ||||
| 5. Round | 22/09/1990 | AFC Ajax | - | FC Volendam | 3:1 | |
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| 6. Round | 29/09/1990 | MVV | - | AFC Ajax | 1:4 | |
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| 7. Round | 07/10/1990 | AFC Ajax | - | NEC Nijmegen | 7:0 | |
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| 8. Round | 21/10/1990 | FC Utrecht | - | AFC Ajax | 0:0 | ||||
| 9. Round | 28/10/1990 | AFC Ajax | - | PSV Eindhoven | 3:1 | |
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| 10. Round | 03/11/1990 | sc Heerenveen | - | AFC Ajax | 1:4 | |
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| 11. Round | 10/11/1990 | AFC Ajax | - | RKC Waalwijk | 0:0 | ||||
| 13. Round | 01/12/1990 | AFC Ajax | - | FC Den Haag | 5:0 | |
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| 14. Round | 08/12/1990 | Feyenoord | - | AFC Ajax | 0:4 | ||||
| 15. Round | 12/01/1991 | Sparta Rotterdam | - | AFC Ajax | 0:0 | ||||
| 17. Round | 26/01/1991 | Vitesse | - | AFC Ajax | 1:3 | |
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| 18. Round | 02/02/1991 | Willem II | - | AFC Ajax | 3:2 | |
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| 21. Round | 02/03/1991 | AFC Ajax | - | FC Groningen | 1:1 | ||||
| 25. Round | 16/03/1991 | AFC Ajax | - | FC Utrecht | 1:1 | ||||
| 12. Round | 18/03/1991 | Roda JC Kerkrade | - | AFC Ajax | 0:0 |
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