| 1. Round | 18/08/2019 | 1. FC Union Berlin | - | RB Leipzig | 0:4 | ||||
| 2. Round | 24/08/2019 | FC Augsburg | - | 1. FC Union Berlin | 1:1 |  |
|||
| 4. Round | 14/09/2019 | 1. FC Union Berlin | - | Werder Bremen | 1:2 | ||||
| 16. Round | 17/12/2019 | 1. FC Union Berlin | - | 1899 Hoffenheim | 0:2 | ||||
| 33. Round | 20/06/2020 | 1899 Hoffenheim | - | 1. FC Union Berlin | 4:0 | ||||
| 34. Round | 27/06/2020 | 1. FC Union Berlin | - | Fortuna Düsseldorf | 3:0 |  |
Nigeria