| 7. Round | 18/09/2022 | 1. FC Union Berlin | - | VfL Wolfsburg | 2:0 | ||||
| 8. Round | 01/10/2022 | Eintracht Frankfurt | - | 1. FC Union Berlin | 2:0 | ||||
| 10. Round | 16/10/2022 | 1. FC Union Berlin | - | Borussia Dortmund | 2:0 |  |
|||
| 13. Round | 06/11/2022 | Bayer Leverkusen | - | 1. FC Union Berlin | 5:0 | ||||
| 21. Round | 19/02/2023 | 1. FC Union Berlin | - | FC Schalke 04 | 0:0 | ||||
| 24. Round | 12/03/2023 | VfL Wolfsburg | - | 1. FC Union Berlin | 1:1 | ||||
| 25. Round | 19/03/2023 | 1. FC Union Berlin | - | Eintracht Frankfurt | 2:0 | ||||
| 33. Round | 20/05/2023 | 1899 Hoffenheim | - | 1. FC Union Berlin | 4:2 | |
Germany