| 22. Round | 23/03/2014 | Zorya Lugansk | - | Metalurh Donetsk | 0:4 |  |
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| 23. Round | 29/03/2014 | Metalurh Donetsk | - | Volyn Lutsk | 1:3 | ||||
| 24. Round | 05/04/2014 | Hoverla Uzhgorod | - | Metalurh Donetsk | 0:0 | ||||
| 25. Round | 11/04/2014 | Metalurh Donetsk | - | PFK Sevastopol | 3:0 | ||||
| 19. Round | 16/04/2014 | Metalurh Donetsk | - | Chernomorets Odessa | 3:2 | ||||
| 26. Round | 19/04/2014 | Shakhtar Donetsk | - | Metalurh Donetsk | 2:1 | ||||
| 27. Round | 27/04/2014 | Metalurh Donetsk | - | Dinamo Kiev | 2:1 | ||||
| 28. Round | 04/05/2014 | Tavriya Simferopol (1958-2014) | - | Metalurh Donetsk | 0:1 | ||||
| 29. Round | 11/05/2014 | Metalurh Donetsk | - | Metalurg Zaporizhya | 2:0 | ||||
| 30. Round | 18/05/2014 | Dnipro Dnipropetrovsk | - | Metalurh Donetsk | 3:1 | |
Greece