| 7. Round | 26/09/2009 | Borussia Dortmund | - | FC Schalke 04 | 0:1 | ||||
| 11. Round | 31/10/2009 | FC Schalke 04 | - | Bayer Leverkusen | 2:2 |  |
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| 12. Round | 07/11/2009 | Bayern München | - | FC Schalke 04 | 1:1 |  |
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| 15. Round | 06/12/2009 | FC Schalke 04 | - | Hertha BSC | 2:0 | ||||
| 16. Round | 12/12/2009 | Werder Bremen | - | FC Schalke 04 | 0:2 | ||||
| 17. Round | 18/12/2009 | FC Schalke 04 | - | 1. FSV Mainz 05 | 1:0 | ||||
| 18. Round | 17/01/2010 | FC Schalke 04 | - | 1. FC Nürnberg | 1:0 | ||||
| 19. Round | 23/01/2010 | VfL Bochum | - | FC Schalke 04 | 2:2 | |
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| 20. Round | 30/01/2010 | FC Schalke 04 | - | 1899 Hoffenheim | 2:0 | ||||
| 21. Round | 06/02/2010 | SC Freiburg | - | FC Schalke 04 | 0:0 | ||||
| 22. Round | 14/02/2010 | FC Schalke 04 | - | 1. FC Köln | 2:0 | ||||
| 23. Round | 21/02/2010 | VfL Wolfsburg | - | FC Schalke 04 | 2:1 | ||||
| 24. Round | 26/02/2010 | FC Schalke 04 | - | Borussia Dortmund | 2:1 | ||||
| 32. Round | 24/04/2010 | Hertha BSC | - | FC Schalke 04 | 0:1 |
Uruguay
Mexico