| 1. Round | 14/07/2013 | Dinamo Kiev | - | Volyn Lutsk | 1:1 | ||||
| 2. Round | 21/07/2013 | Volyn Lutsk | - | Tavriya Simferopol (1958-2014) | 1:0 | ||||
| 3. Round | 27/07/2013 | Metalurg Zaporizhya | - | Volyn Lutsk | 3:0 | ||||
| 4. Round | 03/08/2013 | Volyn Lutsk | - | Dnipro Dnipropetrovsk | 1:3 | ||||
| 6. Round | 19/08/2013 | Volyn Lutsk | - | Karpaty Lviv | 1:1 | ||||
| 7. Round | 24/08/2013 | Vorskla Poltava | - | Volyn Lutsk | 3:3 | ||||
| 8. Round | 01/09/2013 | Volyn Lutsk | - | Metalurh Donetsk | 1:0 | ||||
| 9. Round | 13/09/2013 | Arsenal Kiev | - | Volyn Lutsk | annull. | ||||
| 11. Round | 28/09/2013 | Zorya Lugansk | - | Volyn Lutsk | 2:0 | ||||
| 12. Round | 06/10/2013 | Chernomorets Odessa | - | Volyn Lutsk | 0:0 | ||||
| 14. Round | 27/10/2013 | PFK Sevastopol | - | Volyn Lutsk | 2:1 | ||||
| 15. Round | 01/11/2013 | Volyn Lutsk | - | Shakhtar Donetsk | 2:0 |  |
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| 16. Round | 10/11/2013 | Volyn Lutsk | - | Dinamo Kiev | 1:4 | ||||
| 17. Round | 24/11/2013 | Tavriya Simferopol (1958-2014) | - | Volyn Lutsk | 2:2 | ||||
| 19. Round | 15/04/2014 | Dnipro Dnipropetrovsk | - | Volyn Lutsk | 5:1 | ||||
| 20. Round | 24/04/2014 | Volyn Lutsk | - | Metalist Kharkiv | 1:4 |  |
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| 28. Round | 04/05/2014 | Hoverla Uzhgorod | - | Volyn Lutsk | 6:0 |
Ukraine