| 1. Round | 15/07/2004 | Dnipro Dnipropetrovsk | - | Metalist Kharkiv | 4:2 | ||||
| 2. Round | 20/07/2004 | Metalist Kharkiv | - | Metalurh Donetsk | 1:4 | ||||
| 3. Round | 25/07/2004 | Vorskla-Naftohaz | - | Metalist Kharkiv | 0:1 | ||||
| 4. Round | 01/08/2004 | Metalist Kharkiv | - | Borysfen Boryspil | 3:1 | ||||
| 5. Round | 14/08/2004 | Metalurg Zaporizhya | - | Metalist Kharkiv | 1:4 | ||||
| 6. Round | 29/08/2004 | Metalist Kharkiv | - | Arsenal Kiev | 1:1 | ||||
| 7. Round | 19/09/2004 | FK Obolon | - | Metalist Kharkiv | 0:0 | ||||
| 8. Round | 25/09/2004 | Tavriya Simferopol (1958-2014) | - | Metalist Kharkiv | 1:0 |  |
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| 9. Round | 03/10/2004 | Metalist Kharkiv | - | FK Krivbas (old) | 0:1 | ||||
| 10. Round | 24/10/2004 | Shakhtar Donetsk | - | Metalist Kharkiv | 0:1 | |
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| 13. Round | 11/11/2004 | Metalist Kharkiv | - | FK Illichivets | 1:0 | |
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| 14. Round | 28/11/2004 | Dinamo Kiev | - | Metalist Kharkiv | 3:0 | ||||
| 15. Round | 05/12/2004 | Metalist Kharkiv | - | Chernomorets Odessa | 0:1 | ||||
| 29. Round | 12/06/2005 | Metalurh Donetsk | - | Metalist Kharkiv | 3:1 | ||||
| 30. Round | 16/06/2005 | Metalist Kharkiv | - | Dnipro Dnipropetrovsk | 0:2 |
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