| Group E | 14/09/2004 | Arsenal FC | - | PSV Eindhoven | 1:0 | ||||
| Group E | 29/09/2004 | PSV Eindhoven | - | Panathinaikos | 1:0 | ||||
| Group E | 20/10/2004 | Rosenborg BK | - | PSV Eindhoven | 1:2 | ||||
| Group E | 02/11/2004 | PSV Eindhoven | - | Rosenborg BK | 1:0 | ||||
| Group E | 24/11/2004 | PSV Eindhoven | - | Arsenal FC | 1:1 | ||||
| Group E | 07/12/2004 | Panathinaikos | - | PSV Eindhoven | 4:1 | ||||
| Round of 16 | 22/02/2005 | PSV Eindhoven | - | AS Monaco | 1:0 | ||||
| Round of 16 | 09/03/2005 | AS Monaco | - | PSV Eindhoven | 0:2 |  |
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| Quarter-finals | 05/04/2005 | Olympique Lyonnais | - | PSV Eindhoven | 1:1 | ||||
| Quarter-finals | 13/04/2005 | PSV Eindhoven | - | Olympique Lyonnais | 4:2 pso | ||||
| Semi-finals | 26/04/2005 | AC Milan | - | PSV Eindhoven | 2:0 | ||||
| Semi-finals | 04/05/2005 | PSV Eindhoven | - | AC Milan | 3:1 |
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