| Champions League | Matches | W | D | L |  |
 |
 |
| home | 2 | 2 | - | - | 2 | - | 1 |
| away | 1 | - | - | 1 | 6 | - | - |
| overall | 3 | 2 | - | 1 | 8 | - | 1 |
| Champions League | Home | - | Guest | |
|
|
Results |
| 25/10/00 | Olympiakos Piraeus | - | Valencia CF | 1 | - | - | 1:0 |
| 17/10/01 | Olympiakos Piraeus | - | Lille OSC | 1 | - | 1 | 2:1 |
| 29/10/02 | Bayer Leverkusen | - | Olympiakos Piraeus | 6 | - | - | 2:0 |
Italy