| Champions League | Matches | W | D | L |  |
 |
 |
| home | 4 | 2 | 1 | 1 | 6 | - | - |
| away | 1 | - | - | 1 | 4 | - | - |
| overall | 5 | 2 | 1 | 2 | 10 | - | - |
| Champions League | Home | - | Guest | |
|
|
Results |
| 14/03/12 | Chelsea FC | - | SSC Napoli | 4 | - | - | 4:1 aet |
| 28/09/16 | SSC Napoli | - | SL Benfica | 1 | - | - | 4:2 |
| 01/11/17 | SSC Napoli | - | Manchester City | 2 | - | - | 2:4 |
| 17/09/19 | SSC Napoli | - | Liverpool FC | 1 | - | - | 2:0 |
| 25/02/20 | SSC Napoli | - | FC Barcelona | 2 | - | - | 1:1 |
Germany