| Champions League | Matches | W | D | L |  |
 |
 |
| home | 2 | - | 1 | 1 | 3 | - | 1 |
| away | 1 | - | 1 | - | 3 | - | - |
| overall | 3 | - | 2 | 1 | 6 | - | 1 |
| Champions League | Home | - | Guest | |
|
|
Results |
| 26/02/03 | Valencia CF | - | AS Roma | 1 | - | - | 0:3 |
| 04/04/07 | Chelsea FC | - | Valencia CF | 3 | - | - | 1:1 |
| 28/11/07 | Valencia CF | - | FC Schalke 04 | 2 | - | 1 | 0:0 |
Belgium