| Champions League | Matches | W | D | L |  |
 |
 |
| home | - | - | - | - | - | - | - |
| away | 2 | 1 | - | 1 | 6 | - | - |
| overall | 2 | 1 | - | 1 | 6 | - | - |
| Europa League | Matches | W | D | L | |
|
|
| home | 1 | 1 | - | - | 1 | - | - |
| away | - | - | - | - | - | - | - |
| overall | 1 | 1 | - | - | 1 | - | - |
| Champions League | Home | - | Guest | |
|
|
Results |
| 02/11/05 | SL Benfica | - | Villarreal CF | 3 | - | - | 0:1 |
| 27/09/11 | SSC Napoli | - | Villarreal CF | 3 | - | - | 2:0 |
| Europa League | Home | - | Guest | |
|
|
Results |
| 11/03/04 | Villarreal CF | - | AS Roma | 1 | - | - | 2:0 |
Belgium