| Copa Libertadores | Matches | W | D | L |  |
 |
 |
| home | 3 | 2 | 1 | - | - | - | - |
| away | 1 | - | - | 1 | - | - | - |
| overall | 4 | 2 | 1 | 1 | - | - | - |
| Copa Libertadores | Home | - | Guest | |
|
|
Results |
| 11/02/68 | El Nacional | - | Universidad Católica | - | - | - | 2:1 |
| 18/02/68 | El Nacional | - | Universidad de Chile | - | - | - | 3:1 |
| 03/04/77 | El Nacional | - | Deportivo Cuenca | - | - | - | 0:0 |
| 26/07/78 | LDU Quito | - | El Nacional | - | - | - | 3:2 |
Colombia