| Champions League | Matches | W | D | L |  |
 |
 |
| home | 1 | - | - | 1 | 3 | - | - |
| away | 1 | - | - | 1 | 1 | - | 1 |
| overall | 2 | - | - | 2 | 4 | - | 1 |
| Champions League | Home | - | Guest | |
|
|
Results |
| 11/04/07 | Liverpool FC | - | PSV Eindhoven | 1 | - | 1 | 1:0 |
| 16/09/08 | PSV Eindhoven | - | Atlético Madrid | 3 | - | - | 0:3 |
Italy