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| 1st(1st leg) | Santa Fe | - | Deportivo Pereira | 0:0 (0:0) | ||
| 2nd (2nd leg) | Deportivo Pereira | - | Santa Fe | 2:0 (1:0) | ||
| 1st(1st leg): 28/09/2023 00:15 | 2nd (2nd leg): 05/10/2023 00:00 | Winner: Deportivo Pereira | ||||
| 1st(1st leg) | Águilas Doradas | - | Atlético Nacional | 0:3 (0:1) | ||
| 2nd (2nd leg) | Atlético Nacional | - | Águilas Doradas | 2:1 (1:1) | ||
| 1st(1st leg): 28/09/2023 02:30 | 2nd (2nd leg): 05/10/2023 02:30 | Winner: Atlético Nacional | ||||
| 1st(1st leg) | Cúcuta Deportivo | - | Independiente Medellín | 0:1 (0:0) | ||
| 2nd (2nd leg) | Independiente Medellín | - | Cúcuta Deportivo | 4:5 (0:1) pso | ||
| 1st(1st leg): 28/09/2023 23:00 | 2nd (2nd leg): 06/10/2023 00:00 | Winner: Cúcuta Deportivo | ||||
| 1st(1st leg) | Millonarios | - | Alianza Petrolera | 2:0 (2:0) | ||
| 2nd (2nd leg) | Alianza Petrolera | - | Millonarios | 1:2 (0:0) | ||
| 1st(1st leg): 29/09/2023 01:10 | 2nd (2nd leg): 06/10/2023 02:30 | Winner: Millonarios | ||||
