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| 1st(1st leg) | Macará | - | Independiente del Valle | 0:0 (0:0) | ||
| 2nd (2nd leg) | Independiente del Valle | - | Macará | 2:1 (1:0) | ||
| 1st(1st leg): 06/11/2024 15:00 | 2nd (2nd leg): 10/11/2024 14:30 | Winner: Independiente del Valle | ||||
| 1st(1st leg) | El Nacional | - | Independiente Juniors | 0:2 (0:1) | ||
| 2nd (2nd leg) | Independiente Juniors | - | El Nacional | 2:3 (2:2) | ||
| 1st(1st leg): 06/11/2024 15:00 | 2nd (2nd leg): 10/11/2024 14:00 | Winner: Independiente Juniors | ||||
| 1st(1st leg) | Universidad Católica | - | LDU Quito | 1:0 (1:0) | ||
| 2nd (2nd leg) | LDU Quito | - | Universidad Católica | 0:1 (0:1) | ||
| 1st(1st leg): 06/11/2024 18:00 | 2nd (2nd leg): 10/11/2024 14:00 | Winner: Universidad Católica | ||||
| 1st(1st leg) | Orense SC | - | Aucas | 1:0 (1:0) | ||
| 2nd (2nd leg) | Aucas | - | Orense SC | 1:2 (0:1) | ||
| 1st(1st leg): 06/11/2024 19:00 | 2nd (2nd leg): 10/11/2024 21:00 | Winner: Orense SC | ||||
