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| 1st(1st leg) | SS Cosmos | - | SS Virtus | 0:1 (0:1) | ||
| 2nd (2nd leg) | SS Virtus | - | SS Cosmos | 1:1 (0:1, 0:1) aet | ||
| 1st(1st leg): 04/10/2022 19:45 | 2nd (2nd leg): 19/10/2022 19:45 | Winner: SS Virtus | ||||
| 1st(1st leg) | FC Domagnano | - | AC Libertas | 0:2 (0:0) | ||
| 2nd (2nd leg) | AC Libertas | - | FC Domagnano | 6:2 (3:1) | ||
| 1st(1st leg): 04/10/2022 19:45 | 2nd (2nd leg): 19/10/2022 19:45 | Winner: AC Libertas | ||||
| 1st(1st leg) | FC Fiorentino | - | SP La Fiorita | 0:5 (0:2) | ||
| 2nd (2nd leg) | SP La Fiorita | - | FC Fiorentino | 3:1 (2:0) | ||
| 1st(1st leg): 04/10/2022 19:45 | 2nd (2nd leg): 18/10/2022 19:45 | Winner: SP La Fiorita | ||||
| 1st(1st leg) | SC Faetano | - | SS Murata | 3:1 (1:1) | ||
| 2nd (2nd leg) | SS Murata | - | SC Faetano | 4:0 (2:0) | ||
| 1st(1st leg): 05/10/2022 19:45 | 2nd (2nd leg): 18/10/2022 19:45 | Winner: SS Murata | ||||
| 1st(1st leg) | SS San Giovanni | - | SS Folgore/Falciano | 0:0 (0:0) | ||
| 2nd (2nd leg) | SS Folgore/Falciano | - | SS San Giovanni | 3:2 (1:0, 2:2) aet | ||
| 1st(1st leg): 05/10/2022 19:45 | 2nd (2nd leg): 18/10/2022 19:45 | Winner: SS Folgore/Falciano | ||||
| 1st(1st leg) | SP Tre Penne | - | SS Pennarossa | 0:0 (0:0) | ||
| 2nd (2nd leg) | SS Pennarossa | - | SP Tre Penne | 1:4 (0:2) | ||
| 1st(1st leg): 05/10/2022 19:45 | 2nd (2nd leg): 19/10/2022 19:45 | Winner: SP Tre Penne | ||||
| 1st(1st leg) | AC Juvenes/Dogana | - | SP Cailungo | 2:1 (0:1) | ||
| 2nd (2nd leg) | SP Cailungo | - | AC Juvenes/Dogana | 1:1 (0:0) | ||
| 1st(1st leg): 05/10/2022 19:45 | 2nd (2nd leg): 19/10/2022 19:45 | Winner: AC Juvenes/Dogana | ||||
