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| 1st(1st leg) | Atlético El Vigía | - | Trujillanos FC | 1:1 (1:1) | ||
| 2nd (2nd leg) | Trujillanos FC | - | Atlético El Vigía | 7:6 (0:1, 1:1, 1:1) pso | ||
| 1st(1st leg): 19/05/2013 20:30 | 2nd (2nd leg): 23/05/2013 00:30 | Winner: Trujillanos FC | ||||
| 1st(1st leg) | Real Esppor Club | - | Mineros de Guayana | 0:2 (0:1) | ||
| 2nd (2nd leg) | Mineros de Guayana | - | Real Esppor Club | 2:1 (1:0) | ||
| 1st(1st leg): 19/05/2013 20:30 | 2nd (2nd leg): 23/05/2013 01:00 | Winner: Mineros de Guayana | ||||
| 1st(1st leg) | Deportivo Táchira | - | Atlético Venezuela | 3:2 (1:1) | ||
| 2nd (2nd leg) | Atlético Venezuela | - | Deportivo Táchira | 0:0 (0:0) | ||
| 1st(1st leg): 19/05/2013 22:30 | 2nd (2nd leg): 22/05/2013 21:00 | Winner: Deportivo Táchira | ||||
| 1st(1st leg) | Aragua FC | - | Llaneros de Guanare | 3:0 (1:0) | ||
| 2nd (2nd leg) | Llaneros de Guanare | - | Aragua FC | 2:2 (1:1) | ||
| 1st(1st leg): 19/05/2013 23:30 | 2nd (2nd leg): 22/05/2013 21:30 | Winner: Aragua FC | ||||
