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| 1st(1st leg) | Aragua FC | - | Atlético Venezuela | 1:0 (1:0) | ||
| 2nd (2nd leg) | Atlético Venezuela | - | Aragua FC | 1:1 (0:1) | ||
| 1st(1st leg): 18/05/2014 00:30 | 2nd (2nd leg): 21/05/2014 21:30 | Winner: Aragua FC | ||||
| 1st(1st leg) | Deportivo Lara | - | Carabobo FC | 1:0 (0:0) | ||
| 2nd (2nd leg) | Carabobo FC | - | Deportivo Lara | 3:0 (1:0) | ||
| 1st(1st leg): 18/05/2014 21:30 | 2nd (2nd leg): 21/05/2014 21:00 | Winner: Carabobo FC | ||||
| 1st(1st leg) | Deportivo La Guaira | - | Tucanes FC | 3:1 (1:0) | ||
| 2nd (2nd leg) | Tucanes FC | - | Deportivo La Guaira | 1:0 (0:0) | ||
| 1st(1st leg): 18/05/2014 21:30 | 2nd (2nd leg): 21/05/2014 20:30 | Winner: Deportivo La Guaira | ||||
| 1st(1st leg) | Deportivo Petare | - | Trujillanos FC | 0:2 (0:0) | ||
| 2nd (2nd leg) | Trujillanos FC | - | Deportivo Petare | 5:0 (4:0) | ||
| 1st(1st leg): 18/05/2014 21:30 | 2nd (2nd leg): 21/05/2014 21:30 | Winner: Trujillanos FC | ||||
