Copa Libertadores   M. W D L goals
  at home 2 1 0 1 5 : 4
  Away 2 1 0 1 4 : 3
  4 2 0 2 9 : 7
overall   M. W D L goals
  at home 2 1 0 1 5 : 4
  Away 2 1 0 1 4 : 3
  Neutral Place 0 0 0 0 0 : 0
  4 2 0 2 9 : 7
Copa Libertadores
2006 Group 4 Deportivo Cali - Universidad Católica 2:3 (1:1)
2006 Group 4 Universidad Católica - Deportivo Cali 2:1 (2:1)
1986 Group 4 Universidad Católica - Deportivo Cali 1:3 (1:2)
1986 Group 4 Deportivo Cali - Universidad Católica 3:1 (1:0)

For games that were decided on penalties the score after 120 minutes will be included in the ranking